In electrostatics, all charges are considered to be at rest. Charges in motion constitute an electric current . Such currents occur naturally in many situations, such as lightning, or in steady-state devices like a torch or a cell-driven clock.
Imagine a small area held normal to the direction of flow of charges. Let $q_+$ be the net positive charge flowing in the forward direction, and $q_-$ be the net negative charge flowing in the forward direction. The net charge flowing across the area in time interval $t$ is:
$$q = q_+ - q_-$$
For a steady flow of charge, the current $I$ is defined as:
$$I = \frac{q}{t}$$
If the rate of flow of charge varies with time, we define the instantaneous current $I(t)$ as:
$$I(t) = \lim_{\Delta t \to 0} \frac{\Delta Q}{\Delta t} = \frac{dQ}{dt}$$
The SI unit of current is the ampere ( A ). Typical current magnitudes include:
In solid conductors (metals), atoms are tightly bound, and the current is carried by negatively charged electrons moving in the background of fixed positive ions. In electrolytic solutions, both positive and negative ions can move.
In the absence of an electric field, electrons undergo random thermal motion, colliding with fixed ions. The direction of velocity after collision is completely random, resulting in a net average velocity of zero:
$$\frac{1}{N} \sum_{i=1}^{N} \mathbf{v}_i = 0$$
When an electric field $\mathbf{E}$ is applied, electrons experience an electric force and begin to drift, establishing a current.
Discovered by G.S. Ohm in 1828, Ohm's law states that the current $I$ flowing through a conductor is directly proportional to the potential difference $V$ across its ends, provided physical conditions like temperature remain constant.
$$V \propto I \implies V = R I$$
where $R$ is the resistance of the conductor. The SI unit of resistance is the ohm ($\Omega$).
For a conductor of length $l$ and cross-sectional area $A$:
Combining these relations gives:
$$R = \rho \frac{l}{A}$$
where $\rho$ is the resistivity of the material. Resistivity depends on the material type and temperature, but not on its dimensions.
Define current density $j$ as the current per unit area normal to the flow:
$$j = \frac{I}{A}$$
The SI unit of current density is A/m² . If $E$ is the uniform electric field in a conductor of length $l$, then $V = El$. Substituting these into Ohm's law:
$$El = I R = I \left(\rho \frac{l}{A}\right) = \left(\frac{I}{A}\right) \rho l = j \rho l$$
$$E = j \rho \implies \mathbf{E} = \mathbf{j} \rho$$
Alternatively, in terms of conductivity $\sigma = 1/\rho$:
$$\mathbf{j} = \sigma \mathbf{E}$$
Historical Chronicle: Georg Simon Ohm (1787–1854)
Under an applied electric field $\mathbf{E}$, electrons experience an acceleration $\mathbf{a} = -\frac{e\mathbf{E}}{m}$. However, due to continuous random collisions with ions, they do not accelerate indefinitely but acquire a steady average velocity called drift velocity ($\mathbf{v}_d$).
Let $\tau$ be the relaxation time (the average time between successive collisions). The velocity of the $i$-th electron at time $t$ is:
$$\mathbf{V}_i = \mathbf{v}_i - \frac{e\mathbf{E}}{m} t_i$$
Averaging over all $N$ electrons, the average initial thermal velocity $\langle \mathbf{v}_i \rangle = 0$, and the average time elapsed since the last collision is $\tau$:
$$\mathbf{v}_d = -\frac{e\mathbf{E}}{m} \tau$$
Consider a conductor of cross-sectional area $A$. Let $n$ be the number density of free electrons. In a time interval $\Delta t$, the electrons drift a distance $|v_d| \Delta t$. The total charge crossing the area $A$ in time $\Delta t$ is:
$$\Delta Q = n e A |v_d| \Delta t$$
The current $I$ is therefore:
$$I = n e A v_d$$
Substituting the expression for $v_d$ into the current equation:
$$I = n e A \left(\frac{e E \tau}{m}\right) = \frac{n e^2 A \tau}{m} E$$
Since $j = I/A$ and $E = V/l$:
$$j = \left(\frac{n e^2 \tau}{m}\right) E$$
Comparing this with $\mathbf{j} = \sigma \mathbf{E}$, we get the microscopic expressions for conductivity ($\sigma$) and resistivity ($\rho$):
$$\sigma = \frac{n e^2 \tau}{m}$$
$$\rho = \frac{m}{n e^2 \tau}$$
Mobility ($\mu$) is defined as the magnitude of drift velocity per unit electric field:
$$\mu = \frac{|v_d|}{E} = \frac{e \tau}{m}$$
The SI unit of mobility is m² V¹ s¹ .
Mathematical Problem Statement: Estimate the average drift speed of conduction electrons in a copper wire of cross-sectional area 1.0 &× 10&sup7; m² carrying a current of 1.5 A . Assume each copper atom contributes one conduction electron. Density of copper is 9.0 &× 10³ kg/m³ , atomic mass is 63.5 u .
Step-by-Step Algorithmic Solution Trace:
- Calculate the number density $n$ of conduction electrons:$$n = \frac{6.0 \times 10^{23}}{63.5 \text{ g}} \times 9.0 \times 10^6 \text{ g/m}^3 = 8.5 \times 10^{28} \text{ m}^{-3}$$
- Use the drift velocity formula $v_d = \frac{I}{neA}$:$$v_d = \frac{1.5}{(8.5 \times 10^{28}) \times (1.6 \times 10^{-19}) \times (1.0 \times 10^{-7})} = 1.1 \times 10^{-3} \text{ m/s}$$
Final Evaluation Output: $v_d = 1.1 \text{ mm/s}$
Ohm's law is not a fundamental law of nature. Many materials and devices show deviations from linear behavior.
Over a limited temperature range, the resistivity of a metallic conductor is given by:
$$\rho_T = \rho_0 [1 + \alpha(T - T_0)]$$
where $\alpha$ is the temperature coefficient of resistivity , measured in °C¹ or K¹ .
Mathematical Problem Statement: An electric toaster uses nichrome for its heating element. At room temperature ( 27.0 °C ), its resistance is 75.3 Ω . When connected to a 230 V supply, the current settles to 2.68 A . Find the steady temperature of the element if $\alpha = 1.70 \times 10^{-4} \text{ °C}^{-1}$.
Step-by-Step Algorithmic Solution Trace:
- Calculate the resistance $R_2$ at the steady temperature $T_2$:$$R_2 = \frac{V}{I} = \frac{230}{2.68} = 85.8 \text{ }\Omega$$
- Use the temperature dependence formula $R_2 = R_1[1 + \alpha(T_2 - T_1)]$:$$T_2 - T_1 = \frac{R_2 - R_1}{\alpha R_1} = \frac{85.8 - 75.3}{(1.70 \times 10^{-4}) \times 75.3} = 820 \text{ °C}$$
- Find $T_2$:$$T_2 = 820 + 27.0 = 847 \text{ °C}$$
Final Evaluation Output: $T_2 = 847 \text{ °C}$
When charge carriers move through a conductor under a potential difference, they lose potential energy through collisions, which is dissipated as heat.
The energy dissipated as heat in a conductor of resistance $R$ in time interval $\Delta t$ is:
$$\Delta W = I V \Delta t$$
The power $P$ dissipated is:
$$P = I V = I^2 R = \frac{V^2}{R}$$
In power transmission, to minimize power loss $P_c$ in transmission lines of resistance $R_c$, electricity is transmitted at very high voltage $V$:
$$P_c = \frac{P^2 R_c}{V^2}$$
An electrolytic cell maintains a steady current by converting chemical energy. It consists of two electrodes immersed in an electrolyte.
Cells can be combined in series or parallel to obtain desired voltages and currents in a circuit.
For two cells of emfs $\varepsilon_1, \varepsilon_2$ and internal resistances $r_1, r_2$ connected in series:
$$V_{AC} = V_A - V_C = (\varepsilon_1 + \varepsilon_2) - I(r_1 + r_2)$$
The equivalent emf and internal resistance are:
$$\varepsilon_{eq} = \varepsilon_1 + \varepsilon_2$$
$$r_{eq} = r_1 + r_2$$
If one cell is connected with reverse polarity:
$$\varepsilon_{eq} = \varepsilon_1 - \varepsilon_2 \quad (\text{for } \varepsilon_1 > \varepsilon_2)$$
For two cells connected in parallel:
$$\varepsilon_{eq} = \frac{\varepsilon_1 r_2 + \varepsilon_2 r_1}{r_1 + r_2}$$
$$r_{eq} = \frac{r_1 r_2}{r_1 + r_2}$$
In a simpler form:
$$\frac{\varepsilon_{eq}}{r_{eq}} = \frac{\varepsilon_1}{r_1} + \frac{\varepsilon_2}{r_2}$$
$$\frac{1}{r_{eq}} = \frac{1}{r_1} + \frac{1}{r_2}$$
For complex circuits where simple series-parallel rules fail, Kirchhoff's rules are used.
Historical Chronicle: Gustav Robert Kirchhoff (1824–1887)
The Wheatstone bridge is an arrangement of four resistors $R_1, R_2, R_3, R_4$ in a loop with a galvanometer $G$ connected across one diagonal and a source across the other.
Under the balanced condition, no current flows through the galvanometer ($I_g = 0$). Applying Kirchhoff's rules yields the balance condition:
$$\frac{R_2}{R_1} = \frac{R_4}{R_3}$$
This principle is used in practical devices like the meter bridge to measure unknown resistances.
Mathematical Problem Statement: A cubical network of 12 resistors, each of resistance 1 Ω , is connected across diagonally opposite corners to a 10 V battery of negligible internal resistance. Determine the equivalent resistance of the network.
Step-by-Step Algorithmic Solution Trace:
- By symmetry, let the total current entering the cube be $3I$. It splits equally into three branches at the entrance corner, so current in each of these three edges is $I$.
- At the next corners, each current $I$ splits into two equal parts of $I/2$.
- Applying Kirchhoff's loop rule to a closed loop containing the battery:$$-I R - \frac{1}{2} I R - I R + \varepsilon = 0 \implies \varepsilon = \frac{5}{2} I R$$
- The equivalent resistance $R_{eq}$ is defined by $\varepsilon = (3I) R_{eq}$:$$R_{eq} = \frac{\varepsilon}{3I} = \frac{5}{6} R$$
- For $R = 1 \text{ }\Omega$:$$R_{eq} = \frac{5}{6} \text{ }\Omega$$
Final Evaluation Output: $R_{eq} = \frac{5}{6} \text{ }\Omega$